Messi put his penalty kick over the crossbar, Francisco Silva converted Chile's shootout finale and La Rojawon their second straight Copa
America title by beating Argentina 4-2 on penalty kicks following a 0-0 tie Sunday night.
Playing two days after his 29th birthday, Messi lost a final for the third year in a row following an extra-time defeat to Germany in the 2014 World Cup and a penalty-kick loss to host Chile in last year's Copa America.
The five-time FIFA Player of the Year has won four Champions League titles and eight La Liga crowns with Barcelona, but has never taken a trophy with Argentina's senior team.
For its 100th anniversary, South America's championship was expanded to 16 nations and played in the United States, and Argentina was hoping to win a first major title since 1993.
In an ill-tempered match that included an ejection on each side and eight yellow cards, the match was scoreless through regulation and 30 minutes of extra time, with Argentina's Gonzalo Higuain missing a clear goal-scoring opportunity for the third straight final.
Argentina outshot Chile 16-4 and La Roja collapsed three, four and even five defenders around the bearded Messi, then chopped down the diminutive attacker when he tried to accelerate toward the goal.
Messi, who scored five goals in the tournament, had a free kick 28 yards out in the 115th minute after Francisco SIlva fouled him, but the ball deflected off the wall and over the crossbar.
Messi's 35-yard free kick was headed on target by Sergio Aguero in the 10th minute of extra time, and Chile goalkeeper Claudio Bravo jumped extended his right hand to tip the ball over the crossbar.
Argentina goalkeeper Sergio Romero saved the opening kick by Arturo Vidal, and up stepped Messi, the best player of his generation and considered alongside Brazil's Pele and Argentina's Diego Maradona as the sport's greatest ever.
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